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There are numerous Monarchy pages. I like Dave's Royal Page. From here you can find the rest, I'm sure.
Of course, Britain has no written Constitution, but that doesn't mean it has none at all.
An introduction to it is available at the British Information Services site. You will have to hunt just a little, but check out the page in general. It is very informative, its supposed to be!
The first place to look is the CCTA. It is the official starting point for accessing Her Majesty's Government.
Another good source is The BBC can tell you who are the people in Her Majesty's Government, and those who want to be.
Its easy to vote in the U.K. Just ask Steve and Caroline
Not all the Political Parties have a net presence yet, but all the big ones do.
The Labour Party was the first.
The Conservatives have a nice board.
The Liberal Democrats got on early, too
And here are some others:
The Scottish Nationalist Party
Plaid Cymru
The Ulster Unionist Party
For an nice overview of British Elections since the Second World War, check with the BBC.
David Boothroyd keeps up on British Politics as well as or better than anyone. He has an election statistics page that it really useful. Or try hisBritish Elections and Politics Homepage (with David Taube at the University of London.) Its nice.